Circular birefringence of banded spherulites
WebSep 23, 2024 · A novel 3D growth mechanism of ring-banded spherulite is proposed. 2. Experimental 2.1. Materials and Preparation PBA and PEO were dissolved into chloroform and made into a 2 wt.% polymer solution. PBA was purchased from Aldrich Chemical Company, Inc. (St. Louis, MO, USA), with M w = 12,000 g/mol, T g = −66.2 °C, and T m … WebDec 5, 2024 · The cracks in dendritic spherulites always are roughly random and not regularly circular or spiral shapes as those in circularly ring-banded spherulites. This is readily understandable as the dendritic lamellae in …
Circular birefringence of banded spherulites
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WebThere are two types of spherulites grown from the melt at high temperature (up to 60 °C). The most common is a spherulite from the nonpolar phase (α form), which is larger and has high birefringence and tightly spaced concentric bonding. The second type is smaller and has less birefringence, and comes from the γ phase. WebCircular birefringence of banded spherulites. X Cui, AG Shtukenberg, J Freudenthal, S Nichols, B Kahr. Journal of the American Chemical Society 136 (14), 5481-5490, 2014. 51: 2014: Complete polarimetry on the asymmetric …
WebMar 17, 2024 · Banded spherulitic growth of crystal is observed in some materials with spherically symmetric growth front and periodic radial variation of birefringence. This … Web开馆时间：周一至周日7:00-22:30 周五 7:00-12:00; 我的图书馆
WebApr 8, 2014 · Circular Birefringence of Banded Spherulites Crystal optical properties of banded spherulites of 21 different compounds molecular crystals, polymers, and … WebOct 1, 2015 · There are many other types of “bands” in crystallized spherulites – including “radial stripes” with alternate birefringence colors as bands – periodic bands – because …
WebJul 18, 2016 · Ring-banded PLLA spherulites may be seen when melt-crystallized at 125~140 °C. However, at same Tc, ringless PLLA spherulites are resulted when the samples are subjected to cold …
WebAug 12, 2011 · The circular birefringence of polycrystalline polymers is invariably obscured by strong linear birefringence. To parse the two mechanisms of light retardation, polycrystalline spherulites of... small depth fridge freezerWebThe circular-extinction bands of PDT of nanometer films (300-400 nm) are composed of parallel lamellae with the terrace alignment pointing along the circumferential direction; the... son birthday ecardsWebCircular Birefringence of Banded Spherulites Xiaoyan Cui,†Alexander G. Shtukenberg,*, †John Freudenthal,†Shane Nichols,†Bart Kahr*† †Department of Chemistry, New York … son birthday card adultWebMar 6, 2013 · Mueller matrix imaging reveals radial oscillations in not only linear birefringence, but also circular birefringence, whose origin is explained through slight (∼1.3°) but systematic splaying of individual lamellae in the film. son birthday images for facebookWebThe circular birefringence is shown to be a consequence of misoriented, overlapping anisotropic lamellae, a kind of optical activity associated with the mesoscale … son birthday cards 49th birthdayWebOct 29, 2015 · Neat poly (1,6-hexamethylene adipate) (PHA) is one polyester that never forms ring banded spherulite when crystallized at any crystallization temperatures ( Tc s). However, PHA spherulites readily transform from negative-type at low Tc s (32–38 °C) to positive-type at high Tc s (46–48 °C). son birthday cake with nameWebMar 13, 2014 · Circular Birefringence of Banded Spherulites J. Am. Chem. Soc. March 13, 2014 Other authors. See publication. Twisted … small depth air conditioner